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2022 – Marker Substances in the Aroma of Truffles

11. junio 2022 von sglux

Ruben Epping¹, Lilly Bliesener¹, Dr. Tilman Weiss², Matthias Koch¹, *
¹Division of Organic Trace Analysis and Food Analysis, Bundesanstalt für Materialforschung und -Prüfung, Berlin, Germany
²sglux GmbH, Berlin, Germany
*Authors to whom correspondence should be addressed.

Marker Substances in the Aroma of Truffles

Abstract
The aim of this study was to identify specific truffle marker substances within the truffle aroma. The aroma profile of different truffle species was analyzed using static headspace sampling with gas chromatography mass spectrometry analysis (SHS/GC-MS). Possible marker substances were identified, taking the additional literature into account. The selected marker substances were tested in an experiment with 19 truffle dogs. The hypothesis “If trained truffle dogs recognize the substances as supposed truffles in the context of an experiment, they can be regarded as specific” was made. As it would be nearly impossible to investigate every other possible emitter of the same compounds to determine their specificity, this hypothesis was a reasonable approximation. We were interested in the question of what it is the dogs actually search for on a chemical level and whether we can link their ability to find truffles to one or more specific marker substances. The results of the dog experiment are not as unambiguous as could have been expected based on the SHS/GC-MS measurements. Presumably, the truffle aroma is mainly characterized and perceived by dogs by dimethyl sulfide and dimethyl disulfide. However, as dogs are living beings and not analytical instruments, it seems unavoidable that one must live with some degree of uncertainty regarding these results.

2021 – TOCONs with reduced dead times used for the detection of fire and combustion burner flames

11. junio 2021 von sglux

Dr. Tilman Weiss, sglux GmbH, Berlin, Germany

TOCONs for the detection of fire and combustion burner flames

Abstract
The standard sglux TOCONs are featured by a relatively high time constant that extends from 30 ms (low sensitivity TOCONs) until 80 ms (high sensitivity TOCONs). Most of the TOCON applications benefit from this high time constant because usually the TOCON’s application is to measure a UV irradiation that slowly changes. Such applications are e.g. the control of UV disinfection and UV curing sources. Short changes of signal caused by electromagnetic or high frequency influences are averaged – which is a benefit. However, looking at flame detection in heaters or looking at fire detection applications this relatively high time constant may cause problems. The present report presents opportunities to reduce the dead time of the TOCONs.

2021 – Sensing ultraviolet light emission from hydrogen flames: Flame detection and flame monitoring in CO2 emission free domestic boilers

11. junio 2021 von sglux

Bielefeld, S.E., TU Delft Electrical Engineering, Mathematics and Computer Science

Master Thesis

Abstract
As a contribution to the decarbonisation of domestic heating, the graduation project investigates the feasibility of the application of UV sensor technology for flame detection and flame monitoring in hydrogen-powered domestic gas boilers. The research includes empirical studies and an analytical approach to describe influences on the sensor signal strength.

2020 – UV sensors for hydrogen flame detection

11. junio 2020 von sglux

Dr. Tilman Weiss, sglux GmbH, Berlin, Germany

UV sensors for hydrogen flame detection

Abstract
Pursuing the goal of decarburization of the energy use, the substition of petroleum gas by hydrogen gas produced with renewable energy is a very promising approach.

This requires a certain modification of the heaters. A major change will be the modification of the EN298 compliant flame sensing feature. Currently, sensing petroleum gas flames, electric ionization sensors are used – a rugged, reliable and inexpensive method. However, if hydrogen gas is added to the petroleum gas or if the gas entirely consists of hydrogen these ionization sensors can not be further applied. The reason is a changed reaction kinetics where the ionization effect can not be detected by these conventional sensors. This challenge can be mastered by use of opto-electronic UV sensors. These sensors reliably detect all kind of flames while “seeing” their characteristic emission spectrum in the ultraviolet light range. As UV sensors are more expensive than ionization detectors currently the UV sensors are only applied in highly priced industrial burners but not in household burners. However, according the current state of the knowledge, no other method than opto-electronic UV sensors are able to reliably detect a hydrogen flame.

Since 2006 we produce the TOCONs ABC1 and ABC2 for the EN298 compliant detection of petroleum gas flames in household burners. Our new TOCON_F series is designed for the detection of hydrogen flames.

The difference of the new TOCON_F to the standard ABC1 and ABC2 TOCONs is a reduced off dead-time. This off dead-time occurs with the standard TOCONs when they are saturated and can extend to several 100 milliseconds. The TOCON_F with its logarithmic amplifier shrinks this dead-time to less than 70 milliseconds. Accordingly the reaction time after the flame’s (unwanted) distinction could be strongly increased. Even if the standard TOCONs ABC1 and ABC2 are fast enough (compliant with EN298) to be applied in flame sensing modules (EN298 claims a reaction time of less than 1000 milliseconds) – the requirements of the EN298 standard could be tightened in the future. The reason of this assumption is the significantly higher rate of spread and ignition range of a hydrogen flame compared with a petroleum gas flame. Hence a UV sensor module that works with a TOCON_F offers shorter reaction times than currently required by the standard. This makes these flame sensing modules future-proof in case of a possible revision of the standard.